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Stokes Shift

The difference in wavelength between the absorption and emission maxima of a substance, typically due to vibrational energy level transitions.
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The statement of the theorem

Define νabs\nu_{abs} as the frequency of maximum absorption and νem\nu_{em} as the frequency of maximum emission for a given transition. The Stokes Shift (ΔνS\Delta \nu_S) is defined by the difference in these frequencies:\nΔνS=νemνabs\Delta \nu_S = \nu_{em} - \nu_{abs}