Enthalpy Change of Transition
The heat absorbed or released during a phase transition at a constant pressure, representing the energy difference between the phases.
📜
The statement of the theorem
Let be a thermodynamic system undergoing a phase transition from an initial phase to a final phase at constant pressure . Define the enthalpy as the thermodynamic potential , where is the internal energy. The enthalpy change of transition, , is defined by the path integral along the equilibrium coexistence curve in the plane:\n\n \n\n \n\nAlternatively, using the Clausius-Clapeyron relation for the coexistence curve : \n \nThis yields the rigorous statement for the latent heat (enthalpy change): \n
Source: Wikipedia